Solution-derived poly(ethylene glycol)-TiO x nanocomposite film as a universal cathode buffer layer for enhancing efficiency and stability of polymer solar cells
titanium oxide, nanocomposites, energy conversion, organic solar cells, interface engineering, device stability
Highly efficient and stable polymer solar cells (PSCs) have been fabricated by adopting solution-derived hybrid poly(ethylene glycol)–titanium oxide (PEG–TiOx) nanocomposite films as a novel and universal cathode buffer layer (CBL), which can greatly improve device performance by reducing interface energy barriers and enhancing charge extraction/collection. The performance of inverted PSCs with varied bulk-heterojunctions (BHJs) based on this hybrid nanocomposite CBL was found to be much better than those of control devices with a pure TiOx CBL or without a CBL. An excellent power conversion efficiency up to 9.05% under AM 1.5G irradiation (100 mW·cm–2) was demonstrated, which represents a record high value for inverted PSCs with TiOx-based interface materials.
Tsinghua University Press
Zhigang Yin,Qingdong Zheng,Shan-Ci Chen,Jiaxin Li,Dongdong Cai,Yunlong Ma,Jiajun Wei, Solution-derived poly(ethylene glycol)-TiO x nanocomposite film as a universal cathode buffer layer for enhancing efficiency and stability of polymer solar cells. NanoRes.2015, 8(2): 456–468