Article Title
Synthesis of monodisperse Ce x Zr1−x O2 nanocrystals and the size-dependent enhancement of their properties
Authors
Yuewei Zhang, Key Laboratory for Green Chemical Technology of State Education Ministry, School of Chemical Engineering & Technology, Tianjin University, Tianjin 300072, China
Department of Chemical & Biomolecular Engineering, University of California, Los Angeles, CA 90095, USA
Jing Wen, Key Laboratory for Green Chemical Technology of State Education Ministry, School of Chemical Engineering & Technology, Tianjin University, Tianjin 300072, China
Department of Chemical & Biomolecular Engineering, University of California, Los Angeles, CA 90095, USA
Jun Wang, Key Laboratory for Green Chemical Technology of State Education Ministry, School of Chemical Engineering & Technology, Tianjin University, Tianjin 300072, China
Daocheng Pan, Department of Chemical & Biomolecular Engineering, University of California, Los Angeles, CA 90095, USA
Meiqing Shen, Key Laboratory for Green Chemical Technology of State Education Ministry, School of Chemical Engineering & Technology, Tianjin University, Tianjin 300072, China
Yunfeng Lu, Department of Chemical & Biomolecular Engineering, University of California, Los Angeles, CA 90095, USA
Keywords
Nanocrystals, Ce1–xZrxO2, size-dependent
Abstract
ABSTRACT Monodisperse Ce1–xZrxO2 nanocrystals have been synthesized using a simple two-phase approach; adjusting the ratio of precursors used, amount of capping agent used, reaction time and temperature affords precise control over their composition, structure and size. Size-dependent enhancement of oxygen-storage capacity and kinetics of oxygen storage and release were observed. Systematic studies were conducted in order to understand the size-dependent enhancement of these properties. This work provides important insights into the synthesis and fundamental understanding of multi-component nanocrystals with a large variety of applications.
Graphical Abstract

Publisher
Tsinghua University Press
Recommended Citation
Yuewei Zhang,Jing Wen,Jun Wang,Daocheng Pan,Meiqing Shen,Yunfeng Lu, Synthesis of monodisperse Ce x Zr1−x O2 nanocrystals and the size-dependent enhancement of their properties. NanoRes.2011, 4(5): 494–504
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