Article Title

An electrochemically assisted mechanically controllable break junction approach for single molecule junction conductance measurements

Authors

Yang Yang, State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China
Zhaobin Chen, State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China
Junyang Liu, State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China
Miao Lu, Micro-Electro-Mechanical Systems Research Center, Pen-Tung Sah Micro-Nano Technology Institute, Xiamen University, Xiamen 361005, China
Dezhi Yang, State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China
Fangzu Yang, State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China
Zhongqun Tian, State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China

Keywords

Single molecule junction conductance, electrochemical deposition, mechanically controlled break junction (MCBJ), benzene-1, 4-dithiol, bipyridine

Abstract

We report an electrochemically assisted mechanically controllable break junction (EC-MCBJ) approach to investigating single molecule conductance. Electrode pairs connected with a gold nanobridge were fabricated by electrochemical deposition and then mounted on a homebuilt MCBJ platform. A large number of Au– molecule–Au junctions were produced sequentially by repeated breaking and reconnecting of the gold nanobridge. In order to measure their single molecule conductance, statistical conductance histograms were generated for benzene-1,4-dithiol (BDT) and 4,4’-bipyridine (BPY). The values extracted from these histograms were found to be in the same range as values previously reported in the literature. Our method is distinct from the ones used to acquire these previously reported literature values, however, in that it is faster, simpler, more cost-effective, and changing the electrode material is more convenient.

Graphical Abstract

DOI

https://doi.org/10.1007/s12274-011-0170-5

Publisher

Tsinghua University Press

Recommended Citation

Yang Yang,Zhaobin Chen,Junyang Liu,Miao Lu,Dezhi Yang,Fangzu Yang,Zhongqun Tian, An electrochemically assisted mechanically controllable break junction approach for single molecule junction conductance measurements. NanoRes.2011, 4(12): 1199–1207