Shape control of CoO and LiCoO2 nanocrystals
CoO, LiCoO2, nanocrystals, lithium-ion batteries
Shape control of nanocrystals has become a significant subject in materials science. In this work, we describe a convenient way to achieve morphology-controllable synthesis of CoO nanocrystals including octahedrons and spheres as well as LiCoO2 polyhedrons and spheres. In particular, we explain the formation of CoO octahedrons exposing only high-energy (111) facets using theoretical calculations; these should also be a useful tool for directing future face-controlled preparation of other nanocrystals. More importantly, the as-obtained LiCoO2 nanocrystals showed different electrochemical performance depending on their morphology, indicating that Li-insertion/deintercalation dynamics might be crystal face-sensitive.
Tsinghua University Press
Dingsheng Wang,Xiaoling Ma,Yanggang Wang,Li Wang,Zhongying Wang,Wen Zheng,Xiangming He,Jun Li,Qing Peng,Yadong Li, Shape control of CoO and LiCoO2 nanocrystals. NanoRes.2010, 3: 1–7