CdS magic-size clusters exhibiting one sharp ultraviolet absorption singlet peaking at 361 nm
colloidal semiconductor CdS, magic-size clusters (MSCs), MSC-361, quantum dots (QDs), electronic structures
We report, for the first time, the synthesis of CdS magic-size clusters (MSCs) which exhibit a single sharp absorption peaking at ~ 361 nm, along with sharp band edge photoemission at ~ 377 nm and broad trap emission peaking at ~ 490 nm. These MSCs are produced in a singleensemble form without the contamination of conventional quantum dots (QDs) and/or other-bandgap clusters. They are denoted as MSC-361. We present the details of several controlled syntheses done in oleylamine (OLA), using Cd(NO3)2 or Cd(OAc)2 as a Cd source and thioacetamide (TAA) or elementary sulfur (S) as a S source. A high synthetic reproducibility of the reaction of Cd(NO3)2 and TAA to single-ensemble MSC-361 is achieved, the product of which is not contaminated by other bandgap clusters and/or QDs. In some cases, the reaction product exhibits an additional absorption peak at ~ 322 nm. We demonstrate that the two peaks, at 361 and 322 nm, do not evolve synchronously. Therefore, the 322 nm peak is not a higher order electronic transition of MSC-361, but due to the presence of another ensemble, namely MSC-322. The present study suggests that there is an outstanding need for the development of a physical model to narrow the knowledge gap regarding the electronic structure in these colloidal semiconductor CdS MSCs.
Tsinghua University Press
Junbin Tang,Juan Hui,Meng Zhang,Hongsong Fan,Nelson Rowell,Wen Huang,Yingnan Jiang,Xiaoqin Chen,Kui Yu, CdS magic-size clusters exhibiting one sharp ultraviolet absorption singlet peaking at 361 nm. NanoRes.2019, 12(6): 1437–1444