Article Title

Real-time decay of fluorinated fullerene molecules on Cu(001) surface controlled by initial coverage

Authors

Andrey I. Oreshkin, Department of Physics, Lomonosov Moscow State University, 119991 Moscow, Russia
Dmitry A. Muzychenko, Department of Physics, Lomonosov Moscow State University, 119991 Moscow, Russia
Sergey I. Oreshkin, Sternberg Astronomical Institute, Lomonosov Moscow State University, 119234 Moscow, Russia
Vladimir A. Yakovlev, Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991 Moscow, Russia
Palanichamy Murugan, CSIR Central Electrochemical Research Institute, Karaikudi 630003, Tamil Nadu, India
S. Selva Chandrasekaran, CSIR Central Electrochemical Research Institute, Karaikudi 630003, Tamil Nadu, India
Vijay Kumar, Dr. Vijay Kumar Foundation, 1969 Sector 4, Gurgaon 122001, Haryana, India Center for Informatics, School of Natural Sciences, Shiv Nadar University, NH91, Tehsil Dadari, Gautam Budh Nagar 201 314, Uttar Pradesh, India
Rauf Z. Bakhtizin, Department of Physical Electronics, Bashkir State University, 450074 Ufa, Russia

Keywords

fluorinated fullerene, (001) Cu surface, two-dimensional (2D) molecular island, 2D gas phase, self-assembling molecules, scanning tunneling microscopy (STM), density functional theory (DFT)

Abstract

ABSTRACT In this study, the evolution of C60F18 molecules on a Cu(001) surface was studied by means of scanning tunneling microscopy and density functional theory calculations. The results showed that fluorinated fullerenes (tortoise-shaped polar C60F18) decay on Cu(001) surfaces by a step-by-step detachment of F atoms from the C60 cage. The most favorable adsorption configuration was realized when the F atoms of C60F18 pointed towards the Cu surface and six F atoms were detached from it. The results also showed that a further decay of C60F12 molecules strongly depended on the initial C60F18 coverage. The detached F atoms initially formed a two-dimensional (2D) gas phase which then slowly transformed into F-induced surface structures. The degree of contact between the C60F12 molecules and the Cu(001) surface depended on the density of the 2D gas phase. Hence, the life-time of fluorinated fullerenes was determined by the density of the 2D gas phase, which was affected by the formation of new F-induced structures and the decay of C60F12 molecules.

Graphical Abstract

DOI

https://doi.org/10.1007/s12274-017-1823-9

Publisher

Tsinghua University Press

Recommended Citation

Andrey I. Oreshkin,Dmitry A. Muzychenko,Sergey I. Oreshkin,Vladimir A. Yakovlev,Palanichamy Murugan,S. Selva Chandrasekaran,Vijay Kumar,Rauf Z. Bakhtizin, Real-time decay of fluorinated fullerene molecules on Cu(001) surface controlled by initial coverage. NanoRes.2018, 11(4): 2069–2082