Boron-doped microporous nano carbon as cathode material for high-performance Li-S batteries
boron-doping, microporous carbon, binding energy, Li-S batteries
ABSTRACT In this study, a boron-doped microporous carbon (BMC)/sulfur nanocomposite is synthesized and applied as a novel cathode material for advanced Li-S batteries. The cell with this cathode exhibits an ultrahigh cycling stability and rate capability. After activation, a capacity of 749.5 mAh/g was obtained on the 54th cycle at a discharge current of 3.2 A/g. After 500 cycles, capacity of 561.8 mAh/g remained (74.96% retention), with only a very small average capacity decay of 0.056%. The excellent reversibility and stability of the novel sulfur cathode can be attributed to the ability of the boron-doped microporous carbon host to both physically confine polysulfides and chemically bind these species on the host surface. Theoretical calculations confirm that boron-doped carbon is capable of significantly stronger interactions with the polysulfide species than undoped carbon, most likely as a result of the lower electronegativity of boron. We believe that this doping strategy can be extended to other metal-air batteries and fuel cells, and that it has promising potential for many different applications.
Tsinghua University Press
Feng Wu,Ji Qian,Weiping Wu,Yusheng Ye,Zhiguo Sun,Bin Xu,Xiaoguang Yang,Yuhong Xu,Jiatao Zhang,Renjie Chen, Boron-doped microporous nano carbon as cathode material for high-performance Li-S batteries. NanoRes.2017, 10(2): 426–436