Authors
Dongxu LI, Energy Storage and Conversion Ceramic Materials Engineering Laboratory of Jiangxi Province, China National Light Industry Key Laboratory of Functional Ceramic Materials, School of Materials Science and Engineering, Jingdezhen Ceramic Institute, Jingdezhen 333000, China
Zong-Yang SHEN, Energy Storage and Conversion Ceramic Materials Engineering Laboratory of Jiangxi Province, China National Light Industry Key Laboratory of Functional Ceramic Materials, School of Materials Science and Engineering, Jingdezhen Ceramic Institute, Jingdezhen 333000, China
Zhipeng LI, Energy Storage and Conversion Ceramic Materials Engineering Laboratory of Jiangxi Province, China National Light Industry Key Laboratory of Functional Ceramic Materials, School of Materials Science and Engineering, Jingdezhen Ceramic Institute, Jingdezhen 333000, China
Wenqin LUO, Energy Storage and Conversion Ceramic Materials Engineering Laboratory of Jiangxi Province, China National Light Industry Key Laboratory of Functional Ceramic Materials, School of Materials Science and Engineering, Jingdezhen Ceramic Institute, Jingdezhen 333000, China
Xingcai WANG, Chengdu Hongke Electronic Technology Co., Ltd., Chengdu 610000, China
Zhumei WANG, Energy Storage and Conversion Ceramic Materials Engineering Laboratory of Jiangxi Province, China National Light Industry Key Laboratory of Functional Ceramic Materials, School of Materials Science and Engineering, Jingdezhen Ceramic Institute, Jingdezhen 333000, China
Fusheng SONG, Energy Storage and Conversion Ceramic Materials Engineering Laboratory of Jiangxi Province, China National Light Industry Key Laboratory of Functional Ceramic Materials, School of Materials Science and Engineering, Jingdezhen Ceramic Institute, Jingdezhen 333000, China
Yueming LI, Energy Storage and Conversion Ceramic Materials Engineering Laboratory of Jiangxi Province, China National Light Industry Key Laboratory of Functional Ceramic Materials, School of Materials Science and Engineering, Jingdezhen Ceramic Institute, Jingdezhen 333000, China
Keywords
energy storage ceramics, Ba0.3Sr0.7TiO3 (BST), Bi0.5Na0.5TiO3 (BNT), relaxor ferroelectrics, pulsed power capacitor
Abstract
(Ba0.3Sr0.7)x(Bi0.5Na0.5)1-xTiO3 (BSxBNT, x = 0.3–0.8) ceramics were prepared to investigate their structure, dielectric and ferroelectric properties. BSxBNT ceramics possess pure perovskite structure accompanied from a tetragonal symmetry to pseudo-cubic one with the increase of x value, being confirmed by X-ray diffraction (XRD) and Raman results. The Tm corresponding to a temperature in the vicinity of maximum dielectric constant gradually decreases from 110 ℃ (x = 0.3) to –45 ℃ (x = 0.8), across Tm = 36 ℃ (x = 0.5) with a maximum dielectric constant (ɛr = 5920 @1 kHz) around room temperature. The saturated polarization Ps gradually while the remnant polarization Pr sharply decreases with the increase of x value, making the P–E hysteresis loop of BSxBNT ceramics goes slim. A maximum difference between Ps and Pr (Ps–Pr) is obtained for BSxBNT ceramics with x = 0.5, at which a high recoverable energy density (Wrec = 1.04 J/cm3) is achieved under an applied electric field of 100 kV/cm with an efficiency of η = 77%. Meanwhile, the varied temperature P–E loops, fatigue measurements, and electric breakdown characteristics for the sample with x = 0.5 indicate that it is promising for pulsed power energy storage capacitor candidate materials.
Publisher
Tsinghua University Press
Recommended Citation
Dongxu LI, Zong-Yang SHEN, Zhipeng LI et al. P–E hysteresis loop going slim in Ba0.3Sr0.7TiO3-modified Bi0.5Na0.5TiO3 ceramics for energy storage applications. Journal of Advanced Ceramics 2020, 9(2): 183-192.
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