Electronic structure and enhanced photoelectrocatalytic performance of Ru
Ru, first-principles calculation, electric collector, photoelectric synergistic catalysis
Modification is one of the most important and effective methods to improve the photoelectrocatalytic (PEC) performance of ZnO. In this paper, the RuxZn1-xO/Ti electrodes were prepared by thermal decomposition method and the effect of Ru content on those electrodes’ electronic structure was analyzed through the first-principles calculation. Various tests were also performed to observe the microstructures and PEC performance. The results showed that as the Ru4+ transferred into ZnO lattice and replaced a number of Zn2+, the conduction band of ZnO moved downward and the valence band went upward. The number of photogenerated electron-hole pairs increased as the impurity levels appeared in the band gap. In addition, ZnO nanorods exhibited a smaller grain size and a rougher surface under the effect of Ru. Meanwhile, the RuO2 nanoparticles on the surface of ZnO nanorods acted as the electron-transfer channel, helping electrons transfer to the counter electrode and delaying the recombination of the electron-hole pairs. Specifically, the RuxZn1-xO/Ti electrodes with 9.375 mol% Ru exhibited the best PEC performance with a rhodamine B (RhB) removal rate of 97%, much higher than the combination of electrocatalysis (EC, 12%) and photocatalysis (PC, 50%), confirming the synergy of photoelectrocatalysis.
SHAO, Yanqun; FENG, Keke; GUO, Jie; ZHANG, Rongrong; HE, Sijiang; WEI, Xinli; LIN, Yuting; YE, Zhanghao; and CHEN, Kongfa
"Electronic structure and enhanced photoelectrocatalytic performance of Ru,"
Journal of Advanced Ceramics: Vol. 10:
5, Article 5.
Available at: https://dc.tsinghuajournals.com/journal-of-advanced-ceramics/vol10/iss5/5