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Journal of Advanced Ceramics

Authors

Xin LIU, Key Laboratory of Transparent Opto-functional Inorganic Materials, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201899, China, Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China
Xinglu QIAN, School of Science, Shanghai Institute of Technology, Shanghai 201418, China
Peng ZHENG, College of Materials, Xiamen University, Xiamen 361005, China
Xiaopu CHEN, Key Laboratory of Transparent Opto-functional Inorganic Materials, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201899, China, Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China
Yagang FENG, Key Laboratory of Transparent Opto-functional Inorganic Materials, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201899, China, Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China
Yun SHI, Key Laboratory of Transparent Opto-functional Inorganic Materials, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201899, China, Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China
Jun ZOU, School of Science, Shanghai Institute of Technology, Shanghai 201418, China, Institute of New Materials & Industrial Technology, Wenzhou University, Wenzhou 325024, China
Rongjun XIE, College of Materials, Xiamen University, Xiamen 361005, China
Jiang LI, Key Laboratory of Transparent Opto-functional Inorganic Materials, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201899, China, Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China

Keywords

three-layered composite phosphor, structure design, high color rendering, luminous efficacy

Abstract

A three-layered phosphor structure was designed and prepared by the spin coating of BaSi2N2O2:Eu (cyan-emitting) and (Sr,Ca)AlSiN3:Eu (red-emitting) phosphor films on the yellow- emitting Y3Al5O12:Ce (YAG:Ce) phosphor ceramic synthesized by the solid-state reaction under vacuum sintering. In order to achieve high color rendering lighting, the influence of the composition and structure of the three-layered phosphors on the optical, thermal, and electrical properties of the chip-on-board (COB) packaged white-light-emitting diodes (WLEDs) was studied systematically. The WLED with the structure of "red+cyan+yellow" (R+C+Y) three-layered phosphor generated neutral white light and had a luminous efficacy of 75 lm/W, the fidelity index (Rf) of 93, the gamut index (Rg) of 97, and the correlated color temperature (CCT) of 3852 K. Under the excitation of laser diode (LD), the layer-structured phosphor yielded the white light with a luminous efficacy of 120 lm/W, color rendering index (CRI) of 90, and CCT of 5988 K. The result indicates that the three-layered phosphor structure is a promising candidate to achieve high color rendering and high luminous efficacy lighting.

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